Preheat the oven to 400°F.
Whisk together all honey garlic sauce ingredients in a small bowl. Set aside. Spraying a measuring cup with cooking spray before adding honey helps it slide ride out.
Season chicken thighs all over with salt and pepper, to taste. Dredge chicken thighs in corn starch until lightly coated, shake off excess.
Place chicken thighs in a cast-iron skillet, oven-safe pan, or baking dish and roast for 40-45 minutes or until fully cooked through (165°F internally).
With 20 minutes left on the chicken, prepare rice according to the instructions on the package.
Remove the skillet from the oven and place the chicken on a plate. Transfer the skillet to a burner over medium heat. REMEMBER: The skillet handle will be very hot, don't forget to use oven mitts when handling on the stove. Add the honey garlic sauce and simmer until thickened, about 3 minutes. Be sure to stir to prevent burning
Return chicken to the skillet to toss/coat in the sauce. Serve over jasmine rice and garnish with sesame seeds, green onions, and extra lime wedges.